X-Ray Photoelectron Spectroscopy
- Home
- X-Ray Photoelectron Spectroscopy
Types of Techniques
- Inductively coupled plasma-optical emission spectrometry (ICP-OES)
- UV-Vis spectroscopy
- X-Ray fluorescence (XRF)
- Atomic absorption spectroscopy (AAS)
- Time-Resolved Photoluminescence Spectroscopy (TRPL)
- X-Ray Photoelectron Spectroscopy (XPS)
- Auger Electron Spectroscopy (AES)
- Fourier Transform Infrared Spectroscopy (FTIR)
- Atomic Fluorescence Spectroscopy (AFS)
- Infrared (IR) spectroscopy
- Nuclear Magnetic Resonance Spectroscopy
- Time of Flight Secondary Ion Mass Spectrometry (Tof-SIMS)
- Spectrophotometer
- Mössbauer Spectroscopy
- ultra violet photoelectron spectroscopy
- Electron Paramagnetic Resonance (EPR)
- Glow Discharge Optical Emission Spectrometry
- X-ray Reflectivity (XRR)
- Total Reflection-TXRF
- Ion scattering spectroscopy (ISS)
- Rutherford Backscattering Spectrometry (RBS)
- ToF Elestic Recoil Detection
- Spectroscopic Ellipsometry
X-Ray Photoelectron Spectroscopy (XPS)

X-Ray Photoelectron Spectroscopy (XPS), also known as Electron Spectroscopy for Chemical Analysis (ESCA), is a surface-sensitive analytical technique that provides detailed information about the chemical composition, empirical formula, chemical state, and electronic state of the elements present within a material. It is widely used in various fields, including materials science, surface chemistry, catalysis, and semiconductor research.
Principle
Applications
Advantages
Sample Requirement
Principle
XPS is based on the photoelectric effect, where atoms in a material absorb the energy from X-ray photons, leading to the emission of electrons from the core levels. The kinetic energy of the emitted photoelectrons is measured by the spectrometer, and this energy is characteristic of the element and its chemical environment. The binding energy of the photoelectrons can be calculated from their kinetic energy and the energy of the X-ray source, providing information about the electronic structure and chemical state of the elements present in the material. The intensity of the photoelectron peaks is proportional to the concentration of the corresponding element within the analysed volume, allowing for quantitative analysis.
Applications
Aerospace
- Surface analysis of aerospace materials, coatings, and components
- Characterization of oxidation and corrosion
- Analysis of surface contaminants
- Surface characterization of automotive coatings, catalysts, and materials
- Analysis of wear and friction
- Characterization of engine deposits
- Analysis of catalysts, adsorbents, and chemical reactions
- Characterization of surface functional groups
- Study of surface-adsorbate interactions
- Characterization of electronic materials, thin films, and interfaces
- Analysis of surface contamination
- Study of adhesion and bonding
- Surface analysis of defense materials, coatings, and components
- Characterization of explosive residues
- Analysis of chemical warfare agents
- Characterization of energy materials, battery electrodes, solar cells, and fuel cell components
- Analysis of surface oxidation and degradation
- Study of electrode/electrolyte interfaces
- Forensic analysis of surfaces, trace evidence, and contaminants
- Characterization of gunshot residues
- Analysis of document inks and toners
- Characterization of light-emitting materials, coatings, and interfaces
- Analysis of surface defects and impurities
- Study of phosphor materials
- Analysis of biomaterials, implants, and medical device surfaces
- Characterization of surface biocompatibility
- Study of protein adsorption
- Characterization of drug formulations, excipients, and pharmaceutical surfaces
- Analysis of drug delivery systems
- Study of drug-polymer interactions
- Analysis of raw material surfaces, contaminants, and chemical states
- Characterization of surface impurities
- Study of surface modifications
- Characterization of semiconductor surfaces, thin films, interfaces, and contaminants
- Analysis of surface oxidation and defects
- Study of doping profiles
- Analysis of telecommunication materials, coatings, and data storage surfaces
- Characterization of surface properties
- Study of surface degradation
Advantages
- Surface sensitivity: XPS is highly surface-sensitive, providing information about the top few nano-meters of the sample.
- Chemical state analysis: XPS can distinguish between different chemical states of the same element, enabling the study of chemical bonding and oxidation states.
- Quantitative analysis: The intensity of the photoelectron peaks can be used for quantitative elemental analysis.
- Non-destructive: XPS is a non-destructive technique, allowing further analysis or processing of the sample after analysis.
Sample Requirement
- Sample size ~0.1-2.5 cm2.
- Sample thickness ~1.2 cm.
- Samples must be ultra-high vacuum compatible (<108 torr).
X-ray Absorption Spectroscopy (XAS) is a powerful analytical technique used to probe the electronic structure and local atomic environment of materials. It is widely utilized in various fields, including materials science, chemistry, physics, biology, and environmental science, to gain insights into the properties and behaviors of different substances.